Casale SA

A reactor system comprising a multibed catalytic converter including a mixing region upstream of a catalytic bed, the mixing region is arranged to mix a feed gas of the catalytic bed with a mixing gas, the mixing gas is introduced in the mixing region via a plurality of mixing gas feed lines, each of said lines includes at least one flow regulators device so that the amount of mixing gas admitted into the mixing region by each of the mixing gas feed lines is independently controlled.

A method for the control of nitrogen oxides content in the combustion fumes of a thermal power plant is disclosed; the method comprises the on-site production of ammonia by the steps of: electrolysis of water as a source of hydrogen; separation of air as a source of nitrogen, formation of a make-up gas and synthesis of ammonia in a suitable synthesis loop; said on-site produced ammonia, or a solution thereof, is used for a process of reduction of nitrogen oxides in the combustion fumes.

A catalytic synthesis reactor is described, said reactor comprising a catalytic bed with an annular cylindrical shape delimited by a gas inlet header and a gas outlet header, wherein at least one of said headers has a multiple-wall structure comprising an outer perforated plate having a load-bearing function, an expanded metal plate acting as a spacing element, and a thin micro-perforated plate facing the catalyst and having a catalyst's retaining function.

An ammonia burner comprising an ammonia section for ammonia oxidation and a combined heat exchange section for heating a process stream, wherein said ammonia section and heat exchange section are coaxially arranged in a pressure vessel of the burner and the hot nitrogen oxides-containing effluent gas from the ammonia section is directed to a shell side of the heat exchange section so that said effluent gas transfers heat to the process stream.

A method for revamping a catalytic converter wherein: said catalytic converter comprises a pressure vessel and a catalytic cartridge containing at least one catalyst bed, the pressure vessel includes a cylindrical shell with a full aperture and includes a removable cover of said aperture, and the catalytic cartridge is removable through said upper aperture, and the method includes: installing an additional shell over the aperture of the original shell, thus obtaining an axially extended shell of the pressure vessel; providing an axially extended catalytic cartridge having an axially extended room for holding catalyst in the so obtained axially extended shell.

A multi-bed catalytic reactor, particularly for the synthesis of ammonia, wherein the beds have an annular shape, the first bed has L(1)*(V/V(1)) equal to or greater than 50 wherein L(1) is the slenderness ratio of the first bed which is calculated as the axial length over the radial width; V is the total volume of the beds of the reactor and V(1) is the volume of the first bed.

A method for revamping an ammonia-urea plant wherein: the ammonia section is modernized to produce an extra amount of low pressure steam; condensation stage of the high-pressure urea synthesis loop is modified to use part of the condensation heat of the urea stripper vapours to produce medium-pressure steam, said medium-pressure steam is fed to one or more steam users of the urea section, particularly for carbamate decomposition, the input of low-pressure steam to the urea section is balanced by importing the extra low-pressure steam produced in the ammonia section.

A multi-bed ammonia converter comprising a plurality of catalytic beds for converting an input makeup gas into an ammonia-containing product gas comprising a recovery heat exchanger such as a steam superheater or a boiler which is integrated in the ammonia converter and can be partially accommodated in the cavity of an annular bed.

A catalytic bed for a chemical reactor, said catalytic bed having an annular-cylindrical geometry and comprising at least one collector made with a gas-permeable cylindrical wall, containing at least a first catalyst and a second catalyst, wherein the second catalyst has a finer particle size than the first catalyst, and wherein the first catalyst forms a layer of catalyst adjacent to and in contact with said collector.

A process of making ammonium nitrate from nitric acid and ammonia in a tubular reactor internally coated with a ceramic coating.