24M Technologies, Inc.

Embodiments described herein relate to systems and methods for recycling spent batteries. In some aspects, a method of recycling battery materials can include separating an anode material from a first cathode material and a first separator of a spent electrochemical cell. The method further includes washing the anode material, and drying the anode material to form a recycled anode material, and combining the recycled anode material with a second cathode material and a second separator material to form a recycled electrochemical cell. The method can optionally include washing the first cathode material, drying the first cathode material to form a cathode powder; and regenerating the cathode powder to form a regenerated cathode material, and combining the regenerated cathode material with a second anode material and a second separator to form a recycled electrochemical cell.

Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode, An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance. A semi-solid cathode that includes a suspension of an active material and a conductive material in a non-aqueous liquid electrolyte is disposed in the positive electroactive zone, and an anode is disposed in the negative electroactive zone.

Embodiments described herein relate to regeneration of lithium-deficient electrodes (e.g., lithium iron phosphate, LFP). The process includes multiple steps of heat treatment. The first step includes mixing spent electrode material with lithium carbonate. The lithium carbonate and the spent LFP are then subject to a heating process in an all-nitrogen environment. The first heat treatment brings the materials up to about 550° C. to remove excess water and oxygen. The second heat treatment brings the materials up to about 1,000° C., where they are sintered together to form a like-new electrode material.

Embodiments described herein relate generally to electrochemical cells having pre-lithiated semi-solid electrodes, and particularly to semi-solid electrodes that are pre-lithiated during the mixing of the semi-solid electrode slurry such that a solid-electrolyte interface (SEI) layer is formed in the semi-solid electrode before the electrochemical cell formation. In some embodiments, a semi-solid electrode includes about 20% to about 90% by volume of an active material, about 0% to about 25% by volume of a conductive material, about 10% to about 70% by volume of a liquid electrolyte, and lithium (as lithium metal, a lithium-containing material, and/or a lithium metal equivalent) in an amount sufficient to substantially pre-lithiate the active material. The lithium metal is configured to form a solid-electrolyte interface (SEI) layer on a surface of the active material before an initial charging cycle of an electrochemical cell that includes the semi-solid electrode.

Embodiments described herein relate generally to electrochemical cells having pre-lithiated semi-solid electrodes, and particularly to semi-solid electrodes that are pre-lithiated during the mixing of the semi-solid electrode slurry such that a solid-electrolyte interface (SEI) layer is formed in the semi-solid electrode before the electrochemical cell formation. In some embodiments, a semi-solid electrode includes about 20% to about 90% by volume of an active material, about 0% to about 25% by volume of a conductive material, about 10% to about 70% by volume of a liquid electrolyte, and lithium (as lithium metal, a lithium-containing material, and/or a lithium metal equivalent) in an amount sufficient to substantially pre-lithiate the active material. The lithium metal is configured to form a solid-electrolyte interface (SEI) layer on a surface of the active material before an initial charging cycle of an electrochemical cell that includes the semi-solid electrode.

Embodiments described herein relate generally to electrochemical cells with dendrite prevention mechanisms. In some embodiments, an electrochemical cell can include an anode disposed on an anode current collector, a cathode disposed on a cathode current collector, and a separator disposed between the anode and the cathode. In some embodiments, at least one of the anode or the cathode includes a first portion and a second portion, the second portion configured to prevent dendrite formation around an outside edge of the anode and/or the cathode. In some embodiments, the second portion can include an electroactive material disposed on the anode current collector around an outside edge of the anode current collector. In some embodiments, the second portion can include an electroactive material disposed on a pouch material around an outside edge of the anode current collector.

Embodiments described herein relate generally to electrochemical cells and electrodes with carbon-containing coatings. In some embodiments, an electrochemical cell can include an anode disposed on an anode current collector, a cathode disposed on a cathode current collector, and a separator disposed between the anode and the cathode. The separator has a first side adjacent to the cathode and a second side adjacent to the anode. The electrochemical cell further includes a coating layer disposed on the separator. The coating layer reduces dendrite formation in the electrochemical cell. In some embodiments, the coating layer can include hard carbon. In some embodiments, the coating layer can have a thickness between about 100 nm and about 20 μm. In some embodiments, the coating layer can be disposed on the first side of the separator.

Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance. A semi-solid cathode that includes a suspension of an active material and a conductive material in a non-aqueous liquid electrolyte is disposed in the positive electroactive zone, and an anode is disposed in the negative electroactive zone.

Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance. A semi-solid cathode that includes a suspension of an active material and a conductive material in a non-aqueous liquid electrolyte is disposed in the positive electroactive zone, and an anode is disposed in the negative electroactive zone.

Embodiments described herein relate generally to devices, systems and methods of producing high energy density batteries having a semi-solid cathode that is thicker than the anode. An electrochemical cell can include a positive electrode current collector, a negative electrode current collector and an ion-permeable membrane disposed between the positive electrode current collector and the negative electrode current collector. The ion-permeable membrane is spaced a first distance from the positive electrode current collector and at least partially defines a positive electroactive zone. The ion-permeable membrane is spaced a second distance from the negative electrode current collector and at least partially defines a negative electroactive zone. The second distance is less than the first distance. A semi-solid cathode that includes a suspension of an active material and a conductive material in a non-aqueous liquid electrolyte is disposed in the positive electroactive zone, and an anode is disposed in the negative electroactive zone.