HUNAN BRUNP EV RECYCLING CO., LTD.

Provided is a carbon emission monitoring system. The system includes an oxidation device ( 1 ), a gas mixing device ( 2 ), a gas measurement device ( 3 ), and a control device; the oxidation device ( 1 ), the gas mixing device ( 2 ), and the gas measurement device ( 3 ) are sequentially connected; the control device is separately connected to the oxidation device ( 1 ), the gas mixing device ( 2 ), and the gas measurement device ( 3 ); the input end of the oxidation device ( 1 ) receives waste gas, and the output end of the gas measurement device ( 3 ) discharges waste gas.

The present application discloses a nickel-cobalt-manganese ternary positive electrode material nanorod and the use thereof. The chemical general formula of the nickel-cobalt-manganese ternary positive electrode material nanorod is LiNi 1-x-y-z Co x Mn y Al z O 2 , where 0<x<1, 0<y<1, and 0≤z≤0.05; the nickel-cobalt-manganese ternary positive electrode material nanorod has a section diameter of 50-200 nm and a length of 0.1-5 μm. In the present application, a mixed metal salt solution of nickel, cobalt, manganese, aluminum and lithium and 8-hydroxyquinoline are subjected to complex-precipitation to generate a precipitate containing nickel, cobalt, manganese, aluminum and lithium, and then the precipitate is calcined to prepare a ternary positive electrode material nanorod. Unlike traditional processes, no ammonia-nitrogen wastewater is generated in the whole process, and an alcohol used in the process can be directly recovered by means of evaporation and condensation, such that the process is environment-friendly.

The invention belongs to the field of battery material recovery, and discloses a preparation method and application of heterosite phosphate. The method comprises the following steps: mixing lithium iron phosphate with a solvent, adding an acid solution, and adjusting the pH to obtain an acidic lithium iron phosphate liquid; adding a transition metal additive to the acidic lithium iron phosphate liquid, and performing leaching in an intensifying micro-environment, followed by filtrating to obtain heterosite iron phosphate and a lithium-rich solution. The leaching rate of lithium in the leaching solution reaches 90.5-99.9%, and both of the iron and phosphorus content in the leaching solution are less than 0.1 ppm; the recovered heterosite iron phosphate has a purity of 99.9%, and the recovery rate of the heterosite iron phosphate is 99.3%.

Disclosed are a carbon emission accounting method, a device and a system for recycling of waste battery. The carbon emission accounting apparatus includes a data collection unit and an average-value calculation unit. The carbon emission accounting apparatus includes a collection transmission module and a calculation processing module. The method includes: collecting carbon emission data groups for multiple times within a period; and according to the carbon emission data groups and a preset carbon emission accounting formula group, calculating an average carbon emission amount corresponding to data collected for multiple times within the period.

Disclosed is a method for efficiently removing fluorine from a spent lithium battery. The method comprises: mixing aluminum and a sodium hydroxide solution for reaction to obtain a sodium metaaluminate solution; introducing sulfuric acid into the sodium metaaluminate solution, and stirring to react at a certain temperature to obtain a fluorine removal agent; adding a sodium fluoroaluminate seed crystal and the fluorine removal agent into an impurity-removed battery powder leaching solution, introducing a sodium carbonate solution at the same time, performing reaction at a certain temperature, controlling the pH value of a reaction endpoint, and performing solid-liquid separation after the reaction is finished to obtain a fluorine-removed liquid and filter residues; and adding the sodium hydroxide solution into the filter residues for reaction, and performing solid-liquid separation to obtain a filtrate containing fluorine and aluminum, and insoluble residues. According to the present invention, fluorine removal is induced by adding the sodium fluoroaluminate seed crystal; and during fluorine removal, the seed crystal sodium fluoroaluminate is firstly added into the battery leaching solution, and by means of induction of the seed crystal, combination of fluorine and aluminum in the solution can be accelerated to generate sodium hexafluoroaluminate, the reaction time is shortened, the fluorine removal efficiency is improved, and fluorine in the solution can be removed to be lower than 20 mg/L, thereby achieving the purpose of deep fluorine removal.

The present disclosure discloses a preparation method of tungsten-doped cobalt tetraoxide and use thereof. The preparation method includes the following steps: dissolving a tungsten-containing compound and a molybdenum-containing compound in an alkali liquid to obtain a mixed solution; concurrently feeding the mixed solution, a cobalt salt solution, and a complexing agent into a base solution to allow a reaction to obtain a precipitate; roasting the precipitate in an oxygen-containing atmosphere to obtain a roasted material; and soaking the roasted material in a sodium sulfide solution to obtain the tungsten-doped cobalt tetraoxide. In the present disclosure, tungsten is doped, and tungsten has a large atomic radius, which stabilizes an internal structure of the material, expands the ion channel, and improves the cycling performance of the material; and molybdenum is removed through a soaking process, which provides atomic vacancies to further improve a specific capacity of the material.

Disclosed are a preparation method and application of iron phosphate. The preparation method comprises: subjecting iron phosphate waste to calcination, dissolving it in an acid solution, and filtering to obtain filtrate, namely a solution A containing iron phosphorus; stirring a mixed solution of the solution A and a first alkali solution, adjusting pH of the mixed solution to acidity for reaction, and after washing and filtering to obtain second filter residue, namely an amorphous yellow iron phosphate filter cake; subjecting the yellow iron phosphate filter cake to aging and heating, adding phosphoric acid and a second alkali solution for reaction, followed by washing and filtering to obtain third filter residue, namely a basic ammonium iron phosphate filter cake, then drying to obtain basic ammonium iron phosphate crystal powder; and subjecting the basic ammonium iron phosphate crystal powder to calcination for dehydration and cooling to obtain iron phosphate.

This application discloses a cathode material drying device and a cathode material drying production line. The cathode material drying device includes: a rotary kiln, where a kiln head and a kiln tail of the rotary kiln each are provided with a sealing structure and the rotary kiln can rotate relative to the sealing structure; and an exhaust system comprising an air inlet pipe, an air outlet pipe, and a first fan, where the air inlet pipe communicates with the kiln tail of the rotary kiln through the sealing structure; the air outlet pipe communicates with the kiln head of the rotary kiln through the sealing structure; and the first fan is arranged on the air inlet pipe and/or the air outlet pipe, so as to make an air flow direction in the rotary kiln opposite to a delivery direction of a cathode material.

The present disclosure discloses a recycling method of a ternary material micropowder, and use thereof. The recycling method includes: washing the ternary material micropowder with water, and adding a coating agent and an promotor; subjecting a resulting mixture to a reaction under heating and pressurization, and filtering to obtain a coated base material; subjecting the coated base material to sintering, adding an extracting agent to a resulting sintered material, and stirring and filtering to obtain a filter residue; and subjecting the filter residue to drying, sieving, and iron removal to obtain a ternary cathode material. In the present disclosure, the coating agent and the promotor are added to achieve high-pressure hydrothermal coating for the micropowder. The coating agent can optimize the storage performance of the material and increase the life of the material.

The present disclosure discloses a wet process for recovering valuable metals from a lithium battery. In the method, a waste lithium battery powder is subjected to selective leaching under the condition that a hydrogen sulfide gas is introduced through pressurization, such that Mn 2+ , Li + , and Al 3+ metal ions enter a first-stage leaching liquor and nickel, cobalt, copper, and iron exist in a first-stage leaching residue in the form of a sulfide; then a pH of the first-stage leaching liquor is adjusted to remove aluminum and manganese, which achieves extremely thorough metal separation and leads to relatively pure products; a first-stage leaching residue is subjected to leaching in an acid liquor under a negative pressure, such that the sulfides of nickel, cobalt, iron, and copper are dissolved in a second-stage leaching liquor, and a hydrogen sulfide gas produced can be recycled in the first-stage leaching procedure through pressurization.